Modification of oxysulfides with two nanoparticulate cocatalysts to achieve enhanced hydrogen production from water with visible light.

نویسندگان

  • Fuxiang Zhang
  • Kazuhiko Maeda
  • Tsuyoshi Takata
  • Kazunari Domen
چکیده

Modification of oxysulfides, such as Sm(2)Ti(2)S(2)O(5) and Gd(2)Ti(2)S(2)O(5), with nanoparticulate Rh (reduction site) and Ag(2)S (oxidation site) resulted in enhanced H(2) production from water containing Na(2)S and Na(2)SO(3) as electron donors, showing an apparent quantum yield of 8.8% at 440 nm. This was approximately 9 or 160 times the yield achieved using samples modified with Rh or Ag(2)S, respectively.

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عنوان ژورنال:
  • Chemical communications

دوره 46 39  شماره 

صفحات  -

تاریخ انتشار 2010